Featured Molecules: Metal Chloride Compounds
نویسندگان
چکیده
منابع مشابه
Gating current flowing through molecules in metal-molecules-metal junctions.
We have assembled two junctions that incorporate redox sites between Hg electrodes by different interactions. In the first junction, Hg-SAM-R//R-SAM-Hg, the redox site (R) are covalently linked to each electrode in self assembled monolayers (SAM-R). In the second junction, Hg-SAM//R//SAM-Hg, the redox sites dissolved in solution are trapped by electrostatic interaction at the SAM formed at the ...
متن کاملCopolymerization of Vinyl Chloride by Organometallic Compounds
ABSTRACT The copolymerizations of vinyl chloride with o-olefin or acrylic compounds were investigated with organometallic compounds as catalysts. In general, organoaluminium compounds need to be treated with a complexing agent such as tetrahydrofuran prior to use. Otherwise the former reacts with polyvinyl chloride and loses its activity. The copolymer of vinyl chloride and propylene was thus o...
متن کاملTransition Metal Compounds Towards Holography
We have successfully proposed the application of transition metal compounds in holographic recording media. Such compounds feature an ultra-fast light-induced linkage isomerization of the transition-metal-ligand bond with switching times in the sub-picosecond regime and lifetimes from microseconds up to hours at room temperature. This article highlights the photofunctionality of two of the most...
متن کاملSn(IV) Compounds Interaction with Metal-Schiff Base Complexes
The formation constants and Gibbs free energy for the interaction of RnSnClm (n = m = 2, R = Me, Ph, n-Bu or n = 4, m = 0, R = Ph) compounds as acceptors, with ML complexes (H2L = N,N'-bis(salicylidene)-2-aminobenzylamine (salabza-H2) and its derivatives, M = Mn2+ or Zn2+), as donors in N,N'-dimethylformamide (DMF) as solvent were studied. These parameters were measured by using UV-vis spectrop...
متن کاملControlling the electron transfer mechanism in metal–molecules–metal junctions
We show how the mechanism of electron transfer through molecules can be switched between different regimes by using Hg-based metal–molecules–metal junctions. The junctions are easy to assemble and allow for hosting of self-assembled monolayers (SAMs) of a large variety of molecular structures. In this paper, we compare results from studies of charge transport across two different types of junct...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 2003
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed080p966